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Itoi, Hiroyuki*; Ninomiya, Takeru*; Hasegawa, Hideyuki*; Maki, Shintaro*; Sakakibara, Akihiro*; Suzuki, Ryutaro*; Kasai, Yuto*; Iwata, Hiroyuki*; Matsumura, Daiju; Owada, Mao*; et al.
Journal of Physical Chemistry C, 124(28), p.15205 - 15215, 2020/07
Times Cited Count:8 Percentile:40.15(Chemistry, Physical)Hayashida, Kazuki; Kato, Toshihiro*; Kubota, Mitsuru*; Murakami, Hiroaki; Amano, Yuki; Iwatsuki, Teruki
Chikyu Kagaku, 52(1), p.55 - 71, 2018/03
In this study, the simulated experimental drift was constructed in the granite of 500 m depth at Mizunami Underground Research Laboratory, and the hydrochemical process after the drift closure was observed. The groundwater chemistry around the drift changed with the change of the groundwater flow in the fractures when the gallery was constructed. The redox potential increased due to the infiltration of oxygen from the drift into the rock. After closing the drift, the redox potential of the groundwater plunged due to microbial activity, while the groundwater became alkalized conditon due to the influence of cement material such as shotcrete. The amount of cement material consumed for this alkalization was small, and it was considered that its influence would last long in accordance with the amount of cement used.
Iwase, Masanori*
JNC TJ8400 2000-063, 78 Pages, 2000/03
This study is aimed at controlling oxidation reaction of molten metal by ash in incineration systems, and at positively utilizing the oxidation reaction for decontamination of slag. In this year, in order to investigate physico-chemical properties of mixed fused salt containing alkali sulfates, with special focus on the behaviour of oxygen anion in the melts, Cu / Cu redox equilibrium experiments were carried out. Among the effect of various parameters on Cu / Cu ratio in binary and ternary alkali sulfate melts, the effect of partial pressures of oxygen and SO was mainly investigated in the study. Variation in Cu / Cu ratio were presented as the function of partial pressures of oxygen and SO, respectively. Possible thermodynamic interpretation were made on the experimental results. In addition, the dissolution of CrO in mixed alkali sulfates were also investigated as a first step to elucidate the mechanism of hot corrosion. With this investigation, an important finding was obtained that the solubility of CrO for melts with same average ionic radius, in other words, oxygen ion activity, were essentially identical under constant temperature and atmosphere.
Miki, Takahito*; Sasamoto, Hiroshi; Chiba, Tamotsu*; Inagaki, Manabu*; Yui, Mikazu
JNC TN8400 2000-007, 32 Pages, 2000/01
This report presents a summary of literature survey about geochemical reactions which are important to evaluate the redox conditions in the near field rock mass and buffer. The results of literature survey are summarized as follows; (1)Minerals including ferrous iron and organic materials in the rock mass are important reductants. Initial stage after closure of repository, oxygen will be consumed by pyrite, because the reaction rate between pyrite and oxygen is relatively fast. (2)It is possible to estimate the redox capacity for reductants by rock (mineral)-water iteraction experiment in a laboratory. And it is expected that the ferrous iron-rich rock and higher porosity rock may have bigger redox capacity. (3)It is possible to estimate the oxygen consumption rate by reductants such as minerals including ferrous iron. The rate law and rate constant for the oxidation reaction of ferrous iron in the solution are also determined. As a conclusion, it seems that we can evaluate kinetically the evolution of geochemical conditions in the near field rock mass and buffer by excavation of drifts, based on data derived from these existing literatures.
Yamaguchi, Tetsuji
Genshiryoku Bakkuendo Kenkyu, 6(1), p.147 - 149, 1999/12
no abstracts in English
Oda, Chie; Arthur, R. C,*; Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu; Neyama, Atsushi*
JNC TN8400 99-079, 287 Pages, 1999/09
Two thermodynamic databases for geochemical calculations supporting research and development on geological disposal concepts for high level radioactive waste are described in this report. One, SPRONS.JNC, is compatible with thermodynamic relations comprising the SUPCRT model and software, which permits calculation of the standard molal and partial molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0 to 1000C. This database includes standard molal Gibbs free energies and enthalpies of formation, standard molal entropies and volumes, and Maier-Kelly heat capacity coefficients at the reference pressure (1 bar) and temperature (25C) for 195 minerals and 16 gases. It also includes standard partial molal Gibbs free energies and enthalpies of formation, standard partial molal entropies, and Helgeson, Kirkham and Flowers (HKF) equation-of-state coefficients at the reference pressure and temperature for 1147 inorganic and organic aqueous ions and complexes. SPRONS.JNC extends similar databases described elsewhere by incorporating new and revised data published in the peer-reviewed literature since 1991. The other database, PHREEQE.JNC, is compatible with the PHREEQE series of geochemical modeling codes. It includes equilibrium constants at 25C and 1 bar for mineral-dissolution, gas-solubility, aqueous-association and oxidation-reduction reactions. Reaction enthalpies, or coefficients in an empirical log K(T) function, are also included in this database, which permits calculation of equilibrium constants between 0 and 100C at 1 bar. All equilibrium constants, reaction enthalpies, and logK(T) coefficients in PHREEQE.JNC are calculated usig SUPCRT and SPRONS.JNC, which ensures that these two databases are mutually consistent. They are also internally consistent insofar as all the data are compatible with basic thermodynamic definitions and functional relations in the SUPCRT ...
Kihara, Sorin*; Yoshida, Zenko; Aoyagi, Hisao; Maeda, Koji*; Shirai, Osamu; Kitatsuji, Yoshihiro; Yoshida, Yumi*
Pure and Applied Chemistry, 71(9), p.1771 - 1807, 1999/09
Times Cited Count:55 Percentile:83.61(Chemistry, Multidisciplinary)no abstracts in English
Choppin, G. R.*; Bronikowski, M.*; Chen, J.*; Byegard, J.*; Rai, D.*; Yui, Mikazu
JNC TN8400 99-012, 155 Pages, 1999/01
This report provides thermodynamic data for predicting concentrations of pentavalent and hexavalent actinide species (AnO and AnO) in geologic environments, and contributes to an integration of the JNC chemical thermodynamic database, JNC-TDB (previously PNC-TDB), for the performance analysis of geological isolation system for high-level radioactive wastes. Thermodynamic data for the formation of complexes or compounds with hydroxide, chloride, fluoride, carbonate, nitrate, sulfate and phosphate are discussed in this report. The estimation of the stability constants by use of the Born equation is included. The Pitzer parameters for AnO and AnO, redox potentials and equilibrium constants of redox reactions for actinides are also included.
Tachimori, Shoichi; *
JAERI-Data/Code 96-030, 116 Pages, 1996/10
no abstracts in English
Yokoi, Koichi*; Yoneda, Yoshihiro*; Takahara, Hiroyuki*; Moriya, Toshifumi*
PNC TJ1380 96-002, 68 Pages, 1996/03
None
Kimura, Takaumi
Journal of Radioanalytical and Nuclear Chemistry, 139(2), p.307 - 314, 1990/00
Times Cited Count:2 Percentile:31.34(Chemistry, Analytical)no abstracts in English
Kimura, Takaumi
Journal of Radioanalytical and Nuclear Chemistry, 141(2), p.307 - 316, 1990/00
Times Cited Count:12 Percentile:74.14(Chemistry, Analytical)no abstracts in English
Hoken Butsuri, 22, p.189 - 207, 1987/00
no abstracts in English
Segawa, Takeshi*; Hoshino, Tadaya*; *; *; ; *; *
PNC TN841 74-14, 48 Pages, 1974/06
no abstracts in English
Nagai, Takayuki; Inose, Takehiko*; Sato, Seiichi*; Hatakeyama, Kiyoshi*; Seki, Katsumi*
no journal, ,
no abstracts in English
Irisawa, Eriko; Suzuki, Kazunori*; Kumagai, Mikio*; Kato, Chiaki; Ueno, Fumiyoshi; Abe, Hitoshi
no journal, ,
For the corrosion of stainless steels in the nitric acid solution containing oxidizing metallic ions, it is important factor that the relation between re-oxidation of metallic ions which is reduced with the corrosion reaction and the redox reaction of nitric acid. To make clear the effect of nitrogen oxides formed from nitric acid on oxidation behavior of tetravalent vanadium, changing of concentrations of nitrogen oxide discharged to gas phase from solution and nitrous acid in solution during oxidation reaction of vanadium were measured. The results showed that the nitrogen dioxide acted as oxidant on the oxidation reaction of vanadium.
Okamoto, Yoshihiro; Nagai, Takayuki; Tsuji, Takuya; Matsumura, Daiju
no journal, ,
Some elements such as chromium, iron, rhodium and cerium have multiple valence in the silicate glass. Among them, iron and cerium are known to show a strong mutual correlation in redox behavior. It is reported that Fe (II) is oxidized by Ce (IV) to produce Ce (III) and Fe (III), resulting in the formation of Ce (III) -O-Fe (III) complex in the silicate glass. It is natural to think that if the valence of a constituent element changes in glass, the local structure around that element also changes. In this study, XAFS analysis of Fe and Ce elements was carried out when the Fe content in borosilicate glass was changed, and the changes in the chemical state and local structure were investigated. It was found that by adding Fe, tetravalent Ce (IV) was reduced and the proportion of trivalent Ce (III) increased, and the local structure around Ce also changed accordingly. It was found that Ce was dispersed in the glass phase regardless of whether it was trivalent or tetravalent. However, when Ce was tetravalent, the structural order of the Ce-O pair was as high as that of crystalline CeO.
Watanabe, Yusuke; Terashima, Motoki; Matsueda, Makoto; Koarai, Kazuma; Aoki, Jo; Inoue, Junya
no journal, ,